The
Tip-Sleeve DC resistance should read the same as the
Ring-Sleeve. Measuring from
Tip-Ring should read twice the DC resistance of the previous measurements when taken with your typical multimeter.
That doesn't tell you if one of them is wired backwards and therefore
out of phase, of course, but that is very easy to hear when you listen to any mono or stereo signal. If it is wrong, reverse the
+/- wiring on the pair of leads to either one of the headphone capsule "speaker" drivers and it will cure your phase-reversal problem.
If you want to be fully correct from a technical sense, by convention a positive voltage on a
+ terminal on a speaker driver relative to the
- terminal should normally push outwards on the diaphragm. You won't normally hear a difference in most typical applications regardless of whether
+ is pushing out or
- is pushing out as long as
all the drivers in your system are in phase.Matching phase between disparate units is the reason for the
positive-differential-voltage-is-outward standard convention.
Edit: This gets trickier when you start to add crossovers in speaker systems, etc. where the phase shifts you're dealing with aren't 180-degrees, but that's another topic.